A girl who came from Japan to become a witch. Determined to become a witch after being spellbound by Shiny Chariot's magic show, she decided to attend the Luna Nova Magical Academy. She's not very good at magic, but she's doing her best to make her dream of becoming a witch like Chariot come true with a positive attitude. Her treasure is her Chariot trading card.

A Finnish girl who is Akko's roommate. A kind and sincere girl, she is able to make calm jabs at Akko when she starts getting out of control. Lotte is a good singer, and can even summon Nordic spirits by singing witch folk songs. She is a rabid fan of Nightfall, a novel that revolves around a vampire's bittersweet romance.

Akko's classmate who is said to have come from Southeast Asia, but as she's quite the enigma, no one really knows. She's crazy about poisons, and researches both toxins from animals like spiders and snakes as well as plant poisons from things like mushrooms, sometimes using Akko as her personal guinea pig. She's a sharp-tongued cynic who does things at her own pace.

Akko's British classmate who is from a family of famous witches. She has a brilliant mind and is highly-skilled in magic, leading her to be called the greatest student since Luna Nova's founding. She often butts heads with Akko because of her serious and righteous personality.

A delinquent girl from the United States. A girl with sticky fingers, her hobby is stealing treasure, and even goes so far as to sneak into the school's storehouse and play pranks on the security force. She loves dancing and parties.

A machine-loving German girl who brings in high-tech devices into school despite them being against the rules and sells them after altering them with magic. She seems to be researching something a bit fishy with Sucy, whom she gets along with...

A girl from Russia who loves to eat, and loves nothing more than sweets and peace. She often gets scolded by the teacher for eating snacks during class. Her nickname is Jasna.

The instructor of magic astronomy at Luna Nova Magical Academy. She dotes on and watches over Akko from the shadows as she recklessly runs forward to achieve her dream. There are rumors that she was once Shining Chariot...

A once globally popular witch who caused a magic boom around the world thanks to her magic shows. However, after the boom peaked and eventually died down, she suddenly retired. Her whereabouts are unknown.